Divide it up into skills 'chapters'...then each chapter into projects, or collections of similar work. i.e. Fine Art skills, painting, hand drawing, photography etc Another would be- Computer Skills, show work done on Photoshop, illustrator etc. From experience if your printing images / pages for your folio, do it on glossy paper or something other than the standard printer paper. Add your CV along with it. Another tip; if you have work you are super proud of, put it in your portfolio twice if needs be. I alway put a stand out piece of work in as the very last page with all my information (I may have that piece of work a project earlier in my portfolio.) This is the last thing anyone will see who is looking at your portfolio and the most likely to be remembered.